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The addition of 4mL of 0.005M BaCl2 to 16.0 mL of As2 S3 sol just causes complete coagulation in 2 hrs. What is the flocculating value of the effective ion?

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As2 S3 sol is negatively charged owing to preferential adsorption of S2− ions.

Therefore, cation would be effective ion in coagulation. 

Flocculating value = minimum milli moles of the effective ion per litre of sol

\(=\frac{4\times0.005\times10^3}{4+16}\)

= 1.0

The flocculating value of Ba2+ is 1.0

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