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Types of acid-base titrations 

1. Strong acid vs. strong base (HCl vs. NaOH) 

2. Weak acid vs. strong base (CH3COOH vs. NaOH) 

3. Strong acid vs. weak base (HCl vs. NH4OH) 

• Indicator- Substance which is usually added into the solution taken in the titration flask to detect the equivalence/end point. 

• Indicators which are used in the acid-base titrations are known as pH indicators or neutralisation indicators. 

• An acid-base indicator is a weak organic acid (e.g., phenolphthalein) or weak organic base (e.g., methyl orange). 

• They possess different colour in the acidic and basic medium which indicate the end point in the titration.

• Some commonly used indicators with their pH range are as follows:

Colour change
Indicator pH range Acidic Medium Basic Medium
Methyl Orange 3.2-4.4 Red Yellow
Methyl red 4.8-6.0 Red Yellow
Phenolphthalein 8.2-10.0 Colourless Pink
Thymol blue 8.0-9.6 Yellow blue

Phenolphthalein

It is a weak organic acid (HPh).

Methyl Orange, (MeOH)

It is a weak base.

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