Types of acid-base titrations
1. Strong acid vs. strong base (HCl vs. NaOH)
2. Weak acid vs. strong base (CH3COOH vs. NaOH)
3. Strong acid vs. weak base (HCl vs. NH4OH)
• Indicator- Substance which is usually added into the solution taken in the titration flask to detect the equivalence/end point.
• Indicators which are used in the acid-base titrations are known as pH indicators or neutralisation indicators.
• An acid-base indicator is a weak organic acid (e.g., phenolphthalein) or weak organic base (e.g., methyl orange).
• They possess different colour in the acidic and basic medium which indicate the end point in the titration.
• Some commonly used indicators with their pH range are as follows:
|
Colour change |
Indicator |
pH range |
Acidic Medium |
Basic Medium |
Methyl Orange |
3.2-4.4 |
Red |
Yellow |
Methyl red |
4.8-6.0 |
Red |
Yellow |
Phenolphthalein |
8.2-10.0 |
Colourless |
Pink |
Thymol blue |
8.0-9.6 |
Yellow |
blue |
Phenolphthalein
It is a weak organic acid (HPh).

Methyl Orange, (MeOH)
It is a weak base.

