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A geyser heats water flowing in it at the rate of 50 cc s-1 from 27°C to 77°C. The geyser operates on a gas burner. It consumes 0.6 kg of gas per hour. The heat of combustion of gas is

(1) 6.3 x 104 kJ(kg)-1

(2) 6.3 x 104 J(kg)-1

(3) 6.3 x 103 kJ(kg)-1

(4) 6.3 x 102 kJ(kg)-1

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Best answer

(1) 6.3 x 104 kJ(kg)-1

Heat absorbed by water flowing in 1s

= 50 x 1 x 1 x (77–27) Cal. 

= 2500 Cal. = 2500 x 4.2 J = 1.05 x 104 J

Total heat absorbed in one hour = 1.05 x 104 x 3600 

= 37.8 x 106 J .....(1)

Let α be the heat of combustion of fuel in joule per kg.

Heat liberated by fuel in joule in one hour = 0.6 x α .....(2)

From Eqns (1) and (2) we have

37.8 x 106 = 0.6α

\(∴\alpha=\frac{37.8}{0.6}\times10^6J\,kg^{-1}\)

= 6.3 x 107 J kg-1 = 6.3 x 104 kJ kg-1

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