\(CuCO_3 \xrightarrow{\triangle } CuO + CO_2\)
molar mass of CuCO3 = 123.6 g
\(\therefore\) Number of moles of CuCO3 = \(\frac{80}{123.6}\) = 0.65 g mol
\(\because\) 1 mole of CuCO3 gives = 1 mol CO2
\(\therefore\) 0.65 mol of CuCO3 gives = 0.65 mol CO2
\(\because\) As we know, At room temperature
One mole gas occupy = 22.4 L volume
\(\therefore\) Volume of 0.65 mol CO2 = (22.4 x 0.65) L
= 14.56 L
Hence, On heating 80g CuCO3 produce 14.56 L CO2 gas at room temperature and at atmospheric pressure.