(2) 11.1 eV
According to Bohr’s theory the energy of a photon emitted when it makes a transition from a quantum state n2 to n1 is given by

Also the value of E corresponding to quantum number n is given by En = \(-\frac{13.6}{n^2}eV\)
From above we get
E1 = -13.6 eV
E2 = -3.4 eV
E3 = 0.85 eV
E4 = 0.58 eV
It is clear that 11.1 eV is not obtainable for the difference of any one of the above given values.