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The ionisations enthalpy decreases from Boron to aluminium, but from aluminium to thallium only a marginal increase is observed. Mention the cause for this observation.

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This is due to the presence of inner d and f-electrons which has poor shielding effect compared to s and p-electrons. As a result, the effective nuclear charge on the valance electrons increases. The attraction between the nucleus and valence electron increases. This results in marginal increase in IE from Al to Ga.

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