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The Ks of Ag2CrO4, AgCl, AgBr, and AgI are respectively 1.1 x 10-12, 1.8 x 10-6, 5.0 x 10-13 and 8.3 x 10-17. Which of the following salts will precipitate last of AgNO3 solution containing equal moles of NaCl, NaBr, Nal and Na2CrO4.

(a) AgBr
(b) Ag2CrO4
(c) AgI
(d) AgCl

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(b) Ag2CrO4

As the solubility of Ag2CrO4 is highest, it will be precipitated last at all.

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