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The pair from the following pairs having both compounds with net non-zero dipole moment is 

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The pair from the following pairs having both compounds with net non-zero dipole moment is 

(1) Benzene, anisidine 

(2) 1,4-Dichlorobenzene, 1,3-Dichlorobenzene 

(3) CH2 Cl2 , CHCl3 

(4) cis-butene, trans-butene

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(3) CH2 Cl2 , CHCl3 

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