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(a) You are given a system of two identical particles which may occupy any of three energy levels \(\varepsilon_n\) = n\(\varepsilon\), n = 0, 1,2. The lowest energy state, \(\varepsilon_0\) = 0, is doubly degenerate. The system is in thermal equilibrium at temperature T. For each of the following cases, determine the partition function and the energy and carefully enumerate the configurations.

(1) The particles obey Fermi statistics.

(2) The particles obey Bose statistics.

(3) The (now distinguishable) particles obey Boltzmann statistics.

(b) Discuss the conditions under which fermions or bosons might be treated as Boltzmann particles.

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(a) Denote the two states with \(\varepsilon_0\) = 0 by A and B and the states with \(\varepsilon\) and 2\(\varepsilon\) by 1 and 2 respectively.

(1) The system can have the following configurations if the particles obey fermi statistics: ,

Configuration: (A, B) (A, 1) (B, 1) (A, 2) (B, 2) (1, 2)

Energy: \(0\,\varepsilon\,\varepsilon\,2\varepsilon\,2\varepsilon\,3\varepsilon\)

Thus the partition function is \(​Z = 1 + 2e^{-\varepsilon} + 2e^{-2\varepsilon} + e^{-3\varepsilon} \),

and the mean energy is \(\bar \varepsilon = (2\varepsilon e^{-\varepsilon} + 4\varepsilon e^{-2\varepsilon} + 3\varepsilon e^{-3\varepsilon})/Z\)

(2) If the particles obey Bose statistics, in addition to the above states, the following configurations are also possible:

Configuration: (A, A) (B, B) (1, 1) (2, 2)

Energy: \(0\,0\,2\varepsilon\, 4\varepsilon\)

Hence the partition function and average energy are

(3) for destinguisable particles obeying Boltzmann statistics, more configurations are possible. These are (B, A), (1, A), (1, B), (2, A), (2, B) and (2, 1). Thus we have

(b) Fermions and bosons can be treated as Boltzmann particles when the number of particles is much less than the number of energy levels, for then the exchange effect can be neglected.

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