Correct option is (c) 4.159 g
Molar mass of CuSO4⋅5H2O = 63.5 + 32 + 4 × 16 + 5 × 18 = 249.5 g/mol
Thus, 249.5 g of CuSO4⋅5H2O contains avogadro's number of molecules.
The weight of 1 × 1022 molecules of CuSO4⋅5H2O is \(\frac{249.5}{6.023\times 10^{23}} \times 10^{22}\) = 4.159 g