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The pair n-butyl chloride and isobutyl chloride provides an example of

(a) Chain isomerism 

(b) Optical isomerism 

(c) Geometrical isomerism 

(d) Position isomerism

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(a) Chain isomerism 

The phenomenon of isomerism occurs when two or more compounds have the same chemical formula but distinct chemical structures. Isomers are chemical compounds with identical chemical formulas but differ in characteristics and atom arrangement in the molecule.

n-butyl chloride and iso-butyl chloride both are chain isomers.

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