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Significance of the First Law.

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The first law of thermodynamics leads directly to the non-flow energy equation and embodies four important concepts, as follows: 

1. Heat and work are mutually convertible one into the other as they are both modes of energy transfer. 

2. The existence of a type of energy (internal energy) that depends on the thermodynamic state of a system. 

3. The possibility of measuring a difference in internal energy between thermodynamic states by making measurements of heat transfer and work. 

4. The fact that energy is conserved whenever the thermodynamic state of a closed system changes.

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