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Markownikoff's rule provides guidance of addition of HBr on 

(a) CH2 = CH2 

(b) CH3.CH2.CH3 

(c) CH3. CH = CH.CH3 

(d) CH2 = CHBr

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(d) CH2 = CHBr

According to Markownikoff’s rule H atom or positive part goes to that carbon atom which is more hydrogenated.

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