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Which of the following solution shows positive deviation from Raoult’s law? 

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+1 vote
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in Chemistry by (18.5k points)

Which of the following solution shows positive deviation from Raoult’s law? 

(1) CHCl3 + C6H6 

(2) CH3COCH3 + CS2 

(3) CH3COCH3 + CHCl3 

(4) CH3COCH3 + C6H5NH2

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1 Answer

+1 vote
by (14.2k points)

The correct option is (2) CH3COCH3 + CS2

Acetone and CS2 is an example of solutions showing positive deviation from Raoult’s law. Since acetone – CS2 attractions are weaker than acetone-acetone attractions.

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