Correct option is (4) 23
\({ }_{22} \mathrm{Ti}^{+2} \Rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^2\)
\( { }_{23} \mathrm{~V}^{+2} \Rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^3\)
\({ }_{25} \mathrm{Mn}^{+2} \Rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^5\)
\({ }_{26} \mathrm{Fe}^{+2} \Rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^6\)