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in Physics by (50 points)

What is Go at 25oC for the following reaction

H2 (g) + CO2 (g)  H2O (g) + CO (g)

What is G at 25oC under conditions where the partial pressures of H2, CO2, H2O and CO are 10,20,0.02 and

0.01 atm, respectively?

compound

Gf okJ/mol

H2 (g)

0

CO2 (g)

-394.37

H2O (g)

-228.58

CO (g)

-137.15

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1 Answer

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\(H_2(g) + CO_2(g) \rightleftharpoons H_2O(g) + CO(g)\)

\(Q = \frac{P_{H_2O} \times P_{CO}}{P_{H_2} \times P_{CO_2}}\)

\(= \frac{0.02 \times 0.01}{10 \times 20}\)

\(= 10^{-6}\)

Also,

\(\Delta G^\circ = \Delta_f^\circ G_{CO} + \Delta_f^\circ G_{H_2O} -\Delta_f^\circ G_{CO_2} -\Delta_f^\circ G_{H_2} \)

\(= -137.15 - 228.58 + 394.37 - 0\)

\(= 28.64 \ kJ\)

From the formula,

\(\Delta G = \Delta G^\circ + RT\ln Q\)

\(=28.64 \times 10^3 + 2.303 \times 8.314 \log (10^{-6})\)

\(= 28.64 \times 10^3 - 34.23 \times 10^3\)

\(= -5.6 \ kJ\)

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