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Explain the principle on which the working of a potentiometer is based. Why is the use of potentiometer prferred over that of a voltmeter for measuring the e.m.f. of a cell.

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Principle: The potentiometer is based upon the principle that when a constant current is passed through a wire of uniform area of cross-section, the potential drop across any portion of wire is directly proportional to the length of that portion.

Let V be potential difference across certain portion of wire whose resistance is R. If I is the current through the wire, then

V = IR

We know that R = \(\rho\frac{l}{A}\)

where l, A and ρ are length, area of cross-section and specific resistance of the material of wire respectively.

∴ V = Iρ\(\frac{l}{A}\)

If constant current is passed through the wire of uniform area of cross-section, then ρ, I and A are constants and we have

V    = (constant) l

or V ∝ l

Hence, if a constant current flows through a wire of uniform area of cross-section, then potential drop along the wire is directly proportional to the length of the wire.

(a) Drift Velocity: It is the average velocity of the free electrons with which they get drifted towards the positive terminal under the influence of the external field.

Significance: The net current flowing through any cross-section is controlled by drift velocity and there is no transport of charges in a direction perpendicular to the applied field.

Relaxation Time (τ): The average time between successive collisions of electrons or ions in a conductor is called relaxation time.

Significance: It determines the drift velocity acquired by the electrons under the given applied electric force and also determines the electrical conductivity of a conductor at different temperatures.

(b) In first case:

vd\(\frac{eV}{mL}\tau\)

In second case:

v'd\(\frac{eV\tau}{m5L}\)

v'd\(\frac{1}{5}(\frac{eV}{mL}\tau)\) = \(\frac{v_d}{5}\)

Thus we find that the drift velocity becomes \(\frac{1}{5}\) of its original value.

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