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Absolute alcohol cannot be obtained by simple fractional distillation because 

(a) Pure C2H5OH is unstable 

(b) C2H5OH forms hydrogen bonds with water 

(c) Boiling point of C2H5OH is very close to that of water 

(d) Constant boiling azeotropic mixture is formed with water

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Correct option is (d) Constant boiling azeotropic mixture is formed with water

Based on the chemical nature of ethanol and water, their concentration in the liquid mixture do not alter when heated to its boiling point.

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