For an isothermal change PV = K
Differentiating both the sides, we get
P.dV + V.dP = 0 or V.dP = -PdV
∴ Slope of an isothermal curve,
\((\frac{dP}{dV})_{iso} = -\frac{P}{V}\)
For an adiabatic change, PVγ = K'
Differentiating both sides, we get
P.γVγ-1.dV + Vγ.dP = 0
or γPdV + VdP = 0 or VdP = -γPdV
Slope of an adiabatic curve,
\((\frac{dP}{dV})_{adia} = -\frac{\gamma P}{V}\)
Clearly, slope of an adiabatic curve = γ x slope of an isothermal curve
As, γ > 1, so an adiabatic P - V curve is steeper than the corresponding isothermal P - V curve.