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Which of the following fluorides of xenon is impossible ?

(a) XeF2

(b) XeF3

(c) XeF4

(d) XeF6

1 Answer

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Correct option is (b) XeF3

Xenon is an inert gas. Its electronic configuration is [Kr]4d105s25p6.
All orbitals that are filled have paired electrons.

When one, two or three electrons are promoted from 5p (filled) to 5d (empty) orbitals, two, four and six half-filled orbitals are formed.

Xenon can combine with even number of F atoms to form XeF2, XeF4 or XeF6. It cannot combine with odd number of F atoms.

Thus, formation of XeF3 and XeF5 is not possible.

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