To find the effective atomic number in [Cr(NH3)6]Cl3
Atomic Number of Cr= 24
Oxidation state of Cr= +3
Number of Ligands= 6
We have a formula:
Effective Atomic Number(EAN) = Atomic number + 2(Number of ligands) - Oxidation state
EAN = 24 + 2(6) - 3
EAN = 24 + 12 - 3
EAN = 33
=> Option (D) = 33 is correct.