The correct option is (4) -Q

We are given that, for the circle of radius R, the charge is Q. Potential can be defined as the work done to bring a charge from a reference point to a particular point. We can find the value of charge in the inner circle by using the formula,
\(V = \frac{Q}{4 \pi\varepsilon_0 R} + \frac{q}{4 \pi\varepsilon_0 R}\)
When we equate it to zero, we get
\(V = \frac{Q}{4 \pi\varepsilon_0 R} + \frac{q}{4 \pi\varepsilon_0 R} = 0\)
\(\frac{1}{4\pi\varepsilon_0R} \times (Q + q) = 0\)
We take the constant to the other side and get
Q + q = 0
q = -Q
This gives us the value of charge on the inner circle to be negative of the charge on the outer circle.