Correct option is: (4) 
Those compounds which are more acidic than \(H_2CO_3\) can give effervescence of \(CO_2\) with \(aq. \ NaHCO_3\) .
Release \(CO_2\uparrow\) gas with \(aq. \ NaHCO_3\) .
\(\Rightarrow [A.S.]_{\text{Comp.}} > [A.S.]_{H_2CO_3}\)
\(\rightarrow\) Option 1, 2 and 3 gives effervescence of \(CO_2\) gas with \(NaHCO_3\) .
\(\rightarrow \) Option (4) Not gives \(CO_2\) gas with \(NaHCO_3\).