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ago in Chemistry by (43.7k points)

The number of paramagnetic complex among \([FeF_6]^{3-}, [Fe(CN)_6]^{3-}, [Mn(CN)_6]^{3-}, [Co(C_2O_4)_3]^{3-}, [MnCl_6]^{3-} \ \text{and} \ [CoF_6]^{3-}\) which involved in \(d^2sp^3 \) hybridization is ______.

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Answer is: 2  

\([FeF_6]^{3-}\) Paramagnetic \(sp^3d^2\)
\([Fe(CN)_6]^{3-}\) Paramagnetic \(d^2sp^3\)
\([Mn(CN)_6]^{3-}\) Paramagnetic \(d^2sp^3\)
\([Co(C_2O_4)_3]^{3-}\) Paramagnetic \(d^2sp^3\)
\([MnCl_6]^{3-}\) Paramagnetic \(sp^3d^2\)
\([CoF_6]^{3-}\) Paramagnetic \(sp^3d^2\)

Only  \([Fe(CN)_6]^{3-}\)  and   \([Mn(CN)_6]^{3-}\) are paramagnetic and  \(d^2sp^3\) hybridisation of metal.

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