Correct option is: (3) \(Cr^{2+}> Cr^{3+}> Cu^{2+} > Cu^+\)
\(Cu^+ : [Ar] \ 3d^{10}, \text{Spin only magnetic moment = 0 B.M.}\)
\(Cu^{+2} : [Ar]3d^9, \ \text{Spin only magnetic moment }= \sqrt{3} B.M.\)
\(Cr^{+2} : [Ar]3d^4, \ \text{Spin only magnetic moment = }\sqrt{24} B.M.\)
\(Cr^{+3}:[Ar]3d^3, \ \text{Spin only magnetic moment =}\sqrt{15} B.M.\)
\(\text{Order of }\mu \ : Cr^{+2} > Cr^{+3} > Cu^{+2} > Cu^{+}\)