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 Explain vulcanisation of rubber? 

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Natural rubber becomes soft at high temperatures and brittle at low temperatures. It has a high water absorption capacity. It is soluble in non-polar solvents and is non-resistant to attack by oxidizing agents. 

To improve upon these physical properties, the process of vulcanization is carried out. It consists of heating a mixture of raw rubber with sulphur with a temperature range between 373 K to 415 K. On vulcanisation, sulphur forms cross links at reactive sites of double bonds and thus the rubber gets stiffened.

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