Question

An aromatic compound (a) having molecular formula C₇ H₇ NO₂ dissolves in NaHCO₃ to evolve CO₂ and when reacted with NaNO₂ /HCl forms (b), C₇ H₆ O₃ . (B) dissolves in NaHCO₃ and gives colour reaction with FeCl₃ and can be prepared by the action of CCl₄ and NaOH on phenol. When (B) is reacted with excess HNO₃ , it forms (C), C₆ H₃ N₃ O₇ . (C) undergoes acetylation and decomposes NaHCO₃ to evolve CO₂ . On reaction with PCl₅ (C) is converted to (D), C₆ H₅ N₃ O₆ Cl which when reacted with water gives back (C). Identify compounds (A) to (D).

Answer 1

The compound gives +ve less for NH₂ and COOH