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Aluminium chloride exists as dimer, Al2Cl6 in solid state as well as in solution of non-polar solvents such as benzene.

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Aluminium chloride exists as dimer, Al2Cl6 in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives 

(a) [Al(OH)6]3– + HCl 

(b) [Al(H2O)6]3+ + Cl– 

(c) Al3+ + Cl– 

(d) Al2O3 + HCl

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1 Answer

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Best answer

Correct option (b)

Explanation:

Al2Cl6 + 12H2O ⇋ 2[Al(H2O)6]3+ + 6Cl–

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