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Which one of the following methods is neither meant for the synthesis nor for separation of amines?

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Which one of the following methods is neither meant for the synthesis nor for separation of amines?
(a) Hinsberg method
(b) Hofmann method
(c) Wurtz reaction
(d) Curtius reaction
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(c) :- In Wurtz reaction alkyl halide reacts with sodium metal in the presence of dry ether to give alkane.

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