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A piece of hot metal should be cooled rapidly (quenched) to 25°C, which requires removal of 1000 kJ from the metal. The cold space that absorbs the energy could be one of three possibilities:

(1) Submerge the metal into a bath of liquid water and ice, thus melting the ice.

(2) Let saturated liquid R-22 at −20°C absorb the energy so that it becomes saturated vapor.

(3) Absorb the energy by vaporizing liquid nitrogen at 101.3 kPa pressure.

a.  Calculate the change of entropy of the cooling media for each of the three cases.

b.  Discuss the significance of the results.  

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(a) Melting or boiling at const P & T 

 1Q2 = m(u2 - u1) + Pm(v2 - v1) = m(h2 - h1)

(b) The larger the ∆(1/T) through which the Q is transferred, the larger the ∆S

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