An addition or molecular compound which dissociates into its constituents ions when dissolved in water, is known as double salt. For example,
K2SO4.Al2 (SO4)3.24H2O aq)→ 2K+ (aq) +4SO42- (aq) +2Al3+(aq)
Potash alum (double salt)
Any addition or molecular compound which does not lose its identity in aqueous solution i.e. does not dissociates into its constituent ions. Is known as a coordination compound.For example,
K4 [Fe(CN)6] (aq)→ 4 K+ (aq) + [Fe(CN)6 ]4-(aq)
(Potassium Ferro cyanide)