(i) Haloalkanes dissolve in organic solvents because the new intermolecular attractions between haloalkanes and organic solvent molecules have much the same strength as ones being broken in the separate haloalkanes and solvent molecules.
(ii) An equimolar mixture of a pair of enantiomers is called racemic mixture. For example, butan-2-ol. A racemic mixture is optically inactive due to external compensation.
(iii) Of the two bromo derivatives, C6H5CH(CH3)Br and C6H5CH(C6H5)Br, the intermediate obtained from C6H5CH (C6H5) Br is more stable than obtained from C6H5CH(CH3) Br because it is stabilised by two phenyl groups due to resonance. Therefore, C6H5CH (C6H5)Br is more reactive than C6H5(CH3) Br.