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If for the reaction PbO2 → PbO, ΔG° < 0 

And for the reaction SnO2 → SnO, ΔG° > 0 

What are the most probable oxidation states of Pb and Sn?

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Oxidation states of the elements in the following compounds are

Since PbO2 → PbO change is accompanied by decrease in free energy it is a spontaneous change hence Pb in +2 state is more stable than in +4 state.

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