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in Chemistry by (52.5k points)

Calculate the packing efficiency in Body Centred Cubic (BCC) lattice.

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1 Answer

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by (53.3k points)

In ΔABG, b2 = a2 + a2 

∴ b2 = 2a2

In, ΔAGD, 

C2 = a2 + b2 = a2 + 2a2 

∴ C = \(\sqrt3a\)

Radius of the atom = r. 

Length of the body diagonal C = 4r 

\(\sqrt3a\) = 4r; a = \(\frac{4r}{\sqrt3}\)

Edge length of the cube = a = \(\frac{4r}{\sqrt3}\)

Volume of the cubic unit cell = a3\((\frac{4r}{\sqrt3})^3\)

Volume of one particle (sphere) = \(\frac{4}{3}\)πr3 

The number of particles per unit cell of a BCC = 2

Total volume occupied by two spheres = 2 × \(\frac{4}{3}\)πr3

Packing efficiency = \(\frac{\textit{Total volume occupied by the two spheres}}{\textit{Volume of a cubic unit cell}}\) x 100

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