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In any ac circuit, is the applied instantaneous voltage equal to the algebraic sum of the instantaneous voltages across the series elements of the circuit? Is the same true for rms voltage?

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Yes, the applied instantaneous voltage is equal to the algebraic sum of the instantaneous voltages across the series elements of the circuit. It is because voltages across different elements are not in phase.
It is not true for rms voltages. It is because rms voltages across different elements are not in phase with each other.

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