The gases keep on getting ionised due to energetic rays [X-rays, Cosmic rays, etc.,] passing through them.
However, at atmospheric pressure, the positive and negative ions are too close and recombine to form neutral gas atoms. Due to this, the gases behave as insulatiors at ordinary pressure.
At low pressures, the gas ions do not recombine as they are appreciably apart. Due to the presence of free ions, the gases start conducting at low pressures.