Let, the charge possessed by two conducting spheres of radii a and b be q1 and q2 respectively.
Potential on the surface of first sphere, V1 = \(\frac{1}{4 \pi \varepsilon_0}.\frac{q_1}{a}\)
Potential on the surface of second sphere, V2 = \(\frac{1}{4 \pi \varepsilon_0}.\frac{q_2}{a}\)
Till the potentials of two conductors become equal the flow of charges continue.

Therefore, the ratio of the electric field of first sphere to that of the second sphere is b:a.
The surface charge densities of the two spheres are given as

This implies,
The surface charge densities are inversely proportional to the radii of the sphere.