Force acting on q due to Q1 and Q5 are opposite direction, so cancel to each other. Force acting on q due to Q3 is 
Force acting on q due to Q2 and Q4
Resolving in two component method:
(i) Vertical Component: Q2 Sin θ and Q4 Sinθ are equal and opposite direction, so they are cancel to each other.
(ii) Horizontal Component: Q2 Sin θ and Q4 cos θ are equal and same direction, so they can get added.

Resultant net force F

