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Compare the ionization enthalpies of first series of the transition elements. Ionization enthalpies of first transition series.

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1. Ionization energy of transition element is intermediate between those of s and p block elements. 

2. As we move from left to right in a transition metal series, the ionization enthalpy increases as expected. This is due to increase in nuclear charge corresponding to the filling of d electrons. 

3. The increase in first ionisation enthalpy with increase in atomic number along a particular series is not regular. The added electron enters (n-l)d orbital and the inner electrons act as a shield and decrease the effect of nuclear charge on valence ‘ns’ electrons. Therefore, it leads to variation in the ionization energy values.

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