(a) 3.59 g
AgNO3 + KCl → KNO3 + AgCl
50 mL of 8.5% solution contains 4.25 g of AgNO3
No. of moles of AgNO3 present in 50 mL of 8.5% AgNO3
solution = Mass / (Molar mass)
= 4.25 / 170
= 0.025 moles
Similarly, No of moles of KCl present in loo mL of 1.865% KCl
solution = 1.865 / 74.5
= 0.025 moles
So total amount of AgCl formed is 0.025 moles (based on the stoichiometry)
Amount of AgCl present in 0.025 moles of AgCl = (no. of moles) × (molar mass)
= 0.025 × 143.5
= 3.59 g