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The atmospheric oxidation of NO

2NO(g) + O2(g) ⇌ 2NO2(g)

was studied with initial pressure of 1 atm of NO and 1 atm of O2. At equilibrium, partial pressure of oxygen is 0.52 atm. Calculate Kp of the reaction.

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NO O2 NO2
Initial partial pressure 1 1 -
Reacted 2x x -
Equilibrium partial pressure 1 - 2x 1 - x = 0.52 2x

As, 1 – x = 0.52 

x = 0. 48  

= At equilibrium, 

PNO = 1 – 2x = 1 – 2(0.48) = 0.04 

\(P_{NO_2}\) = 2x = 2(0.48) = 0.96

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