a. Dilute H2SO4 reacts with Fe which is below hydrogen in the electrochemical series, with the evolution of H2.
Fe (Iron) + H2SO4 (Sulphuric acid) → FeSO4 (Ferrous sulphate) + H2 (Hydrogen)
b. When H2SO4 is added to calcium fluoride, hydrogen fluoride is obtained.
CaF2 (Calcium fluoride) + H2SO4 (Sulphuric acid) → CaSO4 (Calcium sulphate) + 2HF (Hydrogen flurode)