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B2 has ten electrons but paramagnetic. Why?

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B, has ten electrons but it is paramagnetic in nature. 

It can be explained by its molecular orbital diagram:

5B = 2, 3 = 1s2 , 2s22p1

5B = 2, 3 = 1s2 , 2s2sp1

Molecular Orbital Configuration

(σ1s)2(σ*1s)2(σ2s)2 (σ*2s)2[(π2px)1(π2py)1]

(σ2pz)0[(π*2p)0 = (π*2p)0] (σ*2pz)0

Since it contains two unpaired electron in π-binding molecular orbitals having equal energy. So, it is paramagnetic in nature.

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