The separation of impurity energy level from conduction band is less in case of n-type semiconductor and more in case of p-type semiconductor. As energy separation of impurity level `=30xx10^(-3)eV` is much smaller than energy gap of pure semiconductor `(~~1eV)`, therefore, the doped semiconductor is n-type.
Here, `E_(g)=30xx10^(-3)eV=kT`
or `T=(30xx10^(-3))/k=(30xx10^(-3))/(8.62xx10^(-5))=348K`