Correct Answer - A
Assertion: Correct statement and reason is correct explanation of assertion.
Green `rarr MnO_(4)^(-) - [Ar]^(18) 3 d^(1) 4 s^(0)`, there is one upaired electron, so paramagnetic.
Purple `rarr MnO_(4)^(2-) - [Ar]^(18) 3 d^(0) 4s^(0)`, here all electrons are paried, so diamagnetic.