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In an electrolysis of an aqueous solution of sodium sulphate, 2.4 litre of oxygen at STP was liberated at anode. The volume of hydrogen at STP liberated at cathode would be

(A) 1.2 L 

(B) 2.4 L 

(C) 2.6 L 

(D) 4.8 L

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Best answer

Correct option (D) 4.8 L

Explanation : 

When aqueous solution of Na2SO4 is electrolysed, the reactions occuring at the two electrodes are

As it is evident that the moles of H2 and O2 liberated at respective electrodes is in the ratio of 2 : 1, so will be the volume ratio at STP.

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