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Which of the following compounds has the most acidic nature?

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Best answer

Correct option (b)

Explanation :

Phenol is most acidic of all the given compounds.

In phenol, the electron withdrawing phenyl ring polarizes the O - H bond thereby facilitating the release of H as H+ and hence phenol is most acidic.

the electron withdrawing effect of phenyl ring is somewhat diminished by the -CH2 group and it is therefore less acidic than phenol. In (c) and (d), -OH group is attached to alkyl groups which, due to their +I effect reduce the polarity of -OH bond and so the acidic strength is low.

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