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Among the following four compounds

(i) Phenol

(ii) Methyl phenol

(iii) Meta-nitrophenol

(iv) Para-nitrophenol

The acidify order is

(a) (iv) > (iii) > (i) > (ii)

(b) (iii) > (iv) > (D > (ii)

(c) (i) > (iv) > (iii) > (ii)

(d) (ii) > (i) > (iii) > (iv)

1 Answer

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Best answer

Correct option (a) (iv) > (iii) > (i) > (ii)

Explanation :

In phenols, the presence of electron releasing groups decrease the acidity, whereas presence of electron withdrawing groups increase the acidity, compared to phenol. Among the meta and para-nitrophenols, the latter is more acidic as the presence of -NO, group at para position stabilises the phenoxide ion to a greater extent than when it is present at meta position. Thus, correct order of acidity is :

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