19. If one of the two electrons of the H2 molecule is removed, we get a hydrogen molecular ion H2+. In the ground state of an H2+, the two protons are separated by roughly 1.5 Å, and the electron is roughly 1 Å from each proton. Determine the potential energy of the system. Specify your choice of the zero of potential energy.
Answer:
Charge of the 1st proton, q1 = 1.6 x 10-19 C
Charge of the 2nd proton, q2 = 1.6 x 10-19 C
Charge of the electron, q3 = -1.6 x 10-19 C
Distance between the 1st and the 2nd proton, d1 = 1.5 x 10-10 m
Distance between the 1st proton and the electron, d2 = 1 x 10-10 m
Distance between the 2nd proton and the electron, d3 = 1 x 10-10 m
The potential energy at infinity is zero
Therefore, the potential energy of the system is
\(V = \frac{q_1q_2}{4\pi\epsilon_0d_1} + \frac{q_2q_3}{4\pi\epsilon_0d_3} + \frac{q_3q_1}{4\pi\epsilon_0d_2}\)
\(V = \frac{1}{4\pi\epsilon_0}\left[\frac{q_1q_2}{d_1}+ \frac{q_2q_3}{d_3}+\frac{q_3q_1}{d_2}\right]\)
Substituting (1/4πε0) = 9 x 109 Nm2C-2 we get
\(V = 9 \times10^9\left[\frac{1.6\times10^{-19}\times1.6\times10^{-19}}{1.5\times10^{10}}+\frac{1.6\times10^{-19}\times(-1.6\times10^{-19})}{1\times10^{-10}}+\frac{(-1.6\times10^{-19})(1.6\times10^{-19})}{1\times10^{10}}\right]\)
\(V = \frac{9\times10^9\times10^{-19}\times10^{-19}}{10^{-10}}\left[\frac{(1.6)^2}{1.5} - (1.6)^2 - (1.6)^2\right]\)
= -30.7 x 10-19 J
= -19.2 eV (1eV = 1.6 x 10-19 J)
Therefore, the potential energy of the system is -19.2 eV.
20. Two charged conducting spheres of radii a and b are connected to each other by a wire. What is the ratio of electric fields at the surfaces of the two spheres? Use the result obtained to explain why the charge density on the sharp and pointed ends of a conductor is higher than on its flatter portions.
Answer:
Let A be the sphere of radius a, Charge QA and capacitance CA
Let B be the sphere of radius b, Charge QB and capacitance CB
The conducting spheres are connected by a wire, therefore the potential of both the capacitors will be V
The electric field due to a, \(E_A = \frac{Q_A}{4\pi\epsilon_0a^2}\)
The electric field due to b, \(E_B = \frac{Q_B}{4\pi\epsilon_0b^2}\)
The ratio of electric fields at the surface of the spheres is
\(\frac{E_A}{E_B} = \frac{Q_A}{4\pi\epsilon_0a^2}\times\frac{b^24\pi\epsilon_0}{Q_B}\)
\(\frac{E_A}{E_B} = \frac{Q_A}{Q_B}\times\frac{b^2}{a^2}\) ........(1)
\(\frac{Q_A}{Q_B} = \frac{C_AV}{C_BV}\)
\(\frac{Q_A}{Q_B} = \frac{a}b\) ..........(2)
Putting equation (2) in equation (1) we get
\(\frac{E_A}{E_B} = \frac{a}{b}\times\frac{b^2}{a^2}\)
Therefore, the ratio of the electric field at the surface is b/a
A sharp and pointed end is like a sphere of very small radius and the flat portion is like a sphere of large radius. Therefore, the charge density is of pointed ends is higher than the flat portion.
21. Two charges –q and +q are located at points (0, 0, –a) and (0, 0, a), respectively.
(a) What is the electrostatic potential at the points (0, 0, z) and (x, y, 0) ?
(b) Obtain the dependence of potential on the distance r of a point from the origin when r/a >> 1.
(c) How much work is done in moving a small test charge from the point (5,0,0) to (–7,0,0) along the x-axis? Does the answer change if the path of the test charge between the same points is not along the x-axis?
Answer:
(a) Two charges –q and +q are located at points (0, 0, –a) and (0, 0, a), respectively. They will form a dipole. The point (0, 0, z) is on the axis of the dipole and (x,y,0) is normal to the dipole. The electrostatic potential at (x,y,0) is zero. The electrostatic potential at (0,0,z) is given by
\(V = \frac{1}{4\pi\epsilon_0}\left(\frac{q}{z-a}\right) + \frac{1}{4\pi\epsilon_0}\left(-\frac{q}{z+a}\right)\)
\(V = \frac{q(z +a-z + a)}{4\pi\epsilon_0(z^2 - a^2)}\)
\(V = \frac{q(2a)}{4\pi\epsilon_0(z^2+a^2)} = \frac{p}{4\pi\epsilon_0(z^2-a^2)}\)
ε0 = Permittivity of free space
p = dipole moment of the system= q x 2a
(b) The distance “r” is much larger than half of the distance between the two charges. Therefore, the potential at the point r is inversely proportional to the square of the distance. i.e., V∝(1/r2).
(c) x, y plane is a equipotential surface and x-axis is a equipotential line. Therefore, the change in potential (dV) along x-axis will be zero. The work done in moving a small test charge from the point (5,0,0) to (–7,0,0) along the x-axis is given by
Potential at (5,0,0)
\(V_1 = \frac{1}{4\pi\epsilon_0}\left(\frac{1}{\sqrt{(5-0)^2-a^2}}\right) + \frac1{4\pi\epsilon_0}(- \frac{q}{\sqrt{(5-0)^2-(-a)^2}}) = 0\)
Potential at (-7,0,0)
\(V_2 = \frac{1}{4\pi\epsilon_0}\left(\frac{1}{\sqrt{((-7)-0)^2 - a^2}}\right) + \frac1{4\pi\epsilon_0}(- \frac{q}{\sqrt{((-7)-0)^2-(-a)^2}}) = 0\)
V2 – V1 = 0
Work done = Charge (q) x Change in Potential (V2 – V1)
Since the change in potential is zero, the work done is also zero.
The change in potential is independent of the path taken between the two points. Therefore, the work done in moving a point charge will remain zero.
22. Figure below shows a charge array known as an electric quadrupole. For a point on the axis of the quadrupole, obtain the dependence of potential on r for r/a >> 1, and contrast your results with that due to an electric dipole, and an electric monopole (i.e., a single charge).

Answer:

Four charges are placed at points A,B,B and C respectively.
Let us consider a point P located at the axis of the quadrupole.
It can be considered that the electric quadrupole has three charges.
The charge +q is placed at A
The charge -2q is placed at B
The charge +q is placed at C
AB = BC = a
BP = r
PA = r + a
PZ = r – a
Therefore, the electrostatic potential due to the system of three charges is

Since r/a >>1,
a/r<< 1
Therefore, a2/r2 is negligible
So we get,
\(V = \frac{2qa^2}{4\pi\epsilon_0r^3}\)
Therefore we get,
V∝ 1/r3
However, for a dipole, V ∝ 1/r2
And for a monopole, V ∝ 1/r