Use app×
Join Bloom Tuition
One on One Online Tuition
JEE MAIN 2025 Foundation Course
NEET 2025 Foundation Course
CLASS 12 FOUNDATION COURSE
CLASS 10 FOUNDATION COURSE
CLASS 9 FOUNDATION COURSE
CLASS 8 FOUNDATION COURSE
0 votes
236 views
in Chemistry by (57.1k points)
closed by

Briefly outline crystal field splitting in square planar complexes.

1 Answer

+1 vote
by (54.9k points)
selected by
 
Best answer

As the lobes of dx2-y2 point towards the ligands, this orbital has the highest energy. The lobes of dxy orbital lie between the ligands but are coplanar with them this orbital is the next highest energy. The lobes of dz2 orbital point out of the plane of the complex but the belt around the centre of the orbital (which contain 1/3 of the electron density) lies in the plane. Therefore dz2 orbital is the next highest in energy. The lobes of dx2 and dy2 orbitals point out of the plane of the complex. Hence, they are least affected by the electrostatic field of the ligands. They are degenerate and lowest in energy.

Welcome to Sarthaks eConnect: A unique platform where students can interact with teachers/experts/students to get solutions to their queries. Students (upto class 10+2) preparing for All Government Exams, CBSE Board Exam, ICSE Board Exam, State Board Exam, JEE (Mains+Advance) and NEET can ask questions from any subject and get quick answers by subject teachers/ experts/mentors/students.

Categories

...